Malaysian
Journal of Analytical Sciences Vol 18 No 2 (2014): 343 – 350
THE EFFECT OF BLEND RATIO ON PROPERTIES OF RECYCLED
POLYPROPYLENE/RECYCLED HIGH DENSITY
POLYETHYLENE GEO-
COMPOSITES
(Kesan Nisbah Adunan Ke Atas Sifat-Sifat Geo-Komposit Polipropilena
Kitar Semula/Polietilena Ketumpatan Tinggi Kitar Semula)
A.A.S Mariam Atiqah, H.Salmah*, Z. Firuz, D.N.U. Lan
School of Materials Engineering,
Universiti Malaysia Perlis,Taman Muhibah, Jejawi,
02600 Arau, Perlis,Malaysia
*Corresponding
author: irsalmah@unimap.edu.my
Abstract
The
effect of blends ratio of Recycled Polypropylene (rPP) and Recycled High
Density Polyethylene (rHDPE) on tensile properties of rPP/rHDPE geo-composites
were studied. The increasing of rHDPE ratios has decreased the tensile strength
and elongation at break of rPP/rHDPE geo-composites, but the modulus of
elasticity increased. The effects of rPP ratios have enhance the tensile
strength and modulus of elasticity of geo-composites. The elongation of break
of rPP/rHDPE was decreased with increasing the rPP content. At similar blends
ratio, the rPP/rHDPE geo-composites higher tensile strength and modulus of
elasticity compared to rHDPE/rPP geo-composites. The MFI value of rPP/rHDPE
higher than rHDPE/rPP blends. The SEM micrograph showed that rPP/rHDPE has
smooth failure surface.
Keywords: recycled polypropylene,
recycled high density polyethylene, tensile properties, blends, geo-composites.
Abstrak
Kesan
nisbah adunan ke atas sifat- sifat tegangan geo komposit polipropilena kitar
semula (rPP)/ polietilena ketumpatan tinggi kitar semula (rHDPE) telah dikaji.
Peningkatan nisbah rHDPE telah mengurangkan kekuatan tegangan dan rPP/rHDPE tetapi meningkatkan ketegangan
modulus. Kesan nisbah rPP telah meningkatkan kekuatan tegangan dan pemanjangan
geo- komposit. Pemanjagan rPP/rHDPE telah menurun dengan peningkatan kandungan
rPP. Pada campuran nisbah yang sama, rPP/rHDPE geo-komposit kekuatan tegangan
modulus tinggi berbanding rHDPE/rPP geo-komposit. Nilai MFI adunan rPP/rHDPE
lebih tinggi berbanding adunan rHDPE/rPP. Mikrograf SEM menunjukkan rPP/rHDPE
mempunyai permukaan yang licin.
Kata kunci: polipropilena
kitar semula, polietilena ketumpatan tinggi kitar semula, sifat-sifat tegangan,
adunan, geo-komposit
References
1.
Rahman
M.M., Islam M.A., Ahmed M. (2012). Recycling of Waste Polymeric Materials as a
Partial Replacement for Aggregate in Concrete. International Conference on
Chemical, Environmental and Biological Sciences (ICCEBS’2012), Penang,
Malaysia.
2.
Sukunya
C. A study of compatibilization and properties of recycled high
densitypolyethylene/polyethylene teraphthalate blends. Institute of
Engineering, Polymer Engineering, Suranaree University of Technology, (2007)
MSc Thesis.
3.
Albano
L. & Sanchez G. (1999). Study of the Mechanical, Thermal and
Thermodegradative Properties of Virgin PP with Recycled and Non Recycled HDPE.
PolymerEngineering and Science. 39(8): 1456-1462.
4.
La
Mantia F. (2002). Handbook of Plastic Recycling. Rapra Technology Ltd.,
Shropshire,UK, London. pg.132-167
5.
Oza
S.,Wang R., Lu N. (2011). Thermal and Mechanical Properties of Recycled High Density
Polyethylene/hemp Fiber Composites.
International Journal of Applied Science
and Technology,1 (5), 31-36.
6.
Batayney
M., Marie I., Asi I. (2007). Use of selected waste materials in concrete mixes.
Faculty of Engineering, Civil Engineering Department, The Hashemite Univeristy,
Jordan. Waste Management, 27:
1870-1876.
7.
Siddique
R., Khatib J., Kaur I. (2008). Use of Recycled plastic in concrete: A review. Waste Management, 28: 1835-1852.
8.
Fasanella
E.L., Jackson E.K., Kellas S. (2007). Soft Soil Impact testing and Simulation
of Aerospace Structures. NASA langley Research Center, Hampton, Virginia, US.
9.
Palmeira
E.M., Tatsuoka F., Bathurst R.J., Stevenson P.E., Zornberg J.G. (2008).
Advances in Geosynthesis Materials and Applications for Soil Reinforcement and
Environmental Protection Works. Electronic
Journal of Geothecnical Engineering: 1 - 38.
10.
Vijay C., John S.K.,Thomas J., George J.N. (2010). World’s First Thermoplastic
Bridges. Parsons Brinckerhoff Inc. New
York.
11.
Pan B., Ning N., Liu J.,Bai L., Fu Q. (2009).
Mechanical Properties of SMC Whisker Reinforced High Density Polyethylene
Composites. Chinese Journal of Polymer Science, 27 (2), 267 – 274.
12.
Lei
Y.,Wu Q.,Yao F.,Xu Y. (2007). Preparation and Properties of recycled
HDPE/natural fiber composites. Composites:
Part A, 38, 1664-1674.
13.
Shenoy A.V., Saini D.R., Nadkarni V.M. (1984).
Melt rheology of polymer blends from melt flow index. International Journal of Polymeric Materials and Polymeric Biomaterials,
10,231-235.
14.
Utracki
L.A. (1983). Melt flow of polymer blends. Polymer
Engineering and Sciences: Polymer Blends. 23(11), 602-609.