Malaysian Journal of Analytical Sciences Vol 18 No 1 (2014): 155 – 161

 

 

 

ANALYSIS AND POLLUTION ASSESSMENT OF HEAVY METAL IN SOIL, PERLIS

 

(Analisis dan Penilaian Pencemaran Logam Berat dalam Tanah, Perlis)

 

Siti Norbaya Mat Ripin1,2*, Sharizal Hasan2, Mohd Lias Kamal2, NorShahrizan Mohd Hashim3

 

1 Faculty of Applied Sciences,

Universiti Teknologi MARA, Malaysia 40450 Shah Alam, Malaysia

2Faculty of Applied Sciences,

3Faculty of Architecture, Planning and Surveying,

Universiti Teknologi Mara Perlis, 02600 Arau Perlis, Malaysia

 

*Corresponding author: norbaya24@gmail.com

 

 

Abstract

Concentration of 5 heavy metals (Cu, Cr, Ni, Cd, Pb) were studied in the soils around Perlis, to assess heavy metals contamination distribution due to industrialization, urbanization and agricultural activities. Soil samples were collected at depth of 0-15cm in eighteen station around Perlis.The soil samples (2mm) were obtained duplicates and subjected to hotblock digestion and the concentration of total metal was determined via ICP-MS. Overall concentrations of Cu, Cr, Ni, Cd and Pb in the soil samples ranged from 0.38-240.59, 0.642-3.921, 0.689-2.398, 0-0.63 and 0.39-27.47 mg/kg respectively. The concentration of heavy metals in the soil display the following decreasing trend: Cu>Pb>Cr>Ni>Cd. From this result, found that level of heavy metal in soil near centralized Chuping industrial areas give maximum value compared with other location in Perlis. The Pollution index revealed that only 11% of Cu and 6% of Cd were classes as heavily contaminated.  Meanwhile, Cu and Pb showed 6% from all samples result a moderately contaminated and the others element give low contamination. Results of combined heavy metal concentration and heavy metal assessment indicate that industrial activities and traffic emission represent most important sources for Cu, Cd and Pb whereas Cr, Ni mainly from natural sources. Increasing anthropogenic influences on the environment, especially pollution loadings, have caused negative changes in natural ecosystems and decreased biodiversity.

 

Keywords: Contamination, Heavy metals, Distribution, ICP-MS, Pollution index

 

References

1.       Soriano, A., Pallarιs, S., Pardo, F., Vicente, A.B., Sanfeliu, T. & Bech, J. (2012).Deposition of heavy metals from particulate settleable matter in soils of an industrialised area. Journal of Geochemical Exploration, 113: 36-44.

2.       Hernandez-Soriano, M.C. & Jimenez-Lopez, J.C. (2012). Effects of soil water content and organic matter addition on the speciation and bioavailability of heavy metals. Science of the Total Environment, 423: 55–61.

3.        Zeng, F., Ali, S., Zhang, H., Ouyang, Y., Qiu, B., Wu, F. & Zhang, G. (2011). The influence of pH and organic matter content in paddy soil on heavy metal availability and their uptake by rice plants. Environmental Pollution, 159: 84-91.

4.       Zhao, H., Xia, B., Fan, C., Zhao, P. & Shen,S. (2012). Human health risk from soil heavy metal contamination under different land uses near Dabaoshan Mine, Southern China. Science of the Total Environment, 417–418:45–54.

5.       Mandal, A. & Voutchkov, M. (2011). Heavy metals in soils around the Cement Factory in Rockfort, Kingston, Jamaica. International Journal of Geosciences, 2:48-54.

6.       Guo, G., Wu, F., Xie, F. & Zhang, R. (2012).Spatial distribution and pollution assessment of heavy metals in urban soils from southwest China. Journal of Environmental Sciences, 24(3): 410–418.

7.       Lu, A., Wang, J., Qin, X., Wang, K., Han, P. & Zhang, S. (2012). Multivariate and geostatistical analyses of the spatial distribution and origin of heavy metals in the agricultural soils in Shunyi, Beijing, China. Science of the Total Environment, 425: 66–74.

8.       Koz, B., Cevik, U. & Akbulut, S. (2012). Heavy metal analysis around Murgul (Artvin) copper mining area of Turkey using moss and soil. Ecological Indicators,20: 17–23.

9.       Lee, C.S., Li, X., Shi, W., Cheung, S.C. & Thornton, I. (2006). Metal contamination in urban, suburban, and country park soils of Hong Kong: A study based on GIS and multivariate statistics. Science of the Total Environment, 356: 45-61.

10.    Adelekan B. A & Abegunde. K. D. (2011). Heavy metals contamination of soil and groundwater at automobile mechanic villages in Ibadan, Nigeria. International Journal of the Physical Sciences 6(5): 1045-1058.

11.    Maas, S., Scheifler, R., Benslama, M., Crini, N., Lucot, E., Brahmia, Z., Benyacoub, S. & Giraudoux,P. (2010). Spatial distribution of heavy metal concentrations in urban, suburban and agricultural soils in a Mediterranean city of Algeria. Environmental Pollution, 158: 2294-2301.

12.    Guven, D.E. & Akinci, G. (2011). Comparison of acid digestion techniques to determine heavy metals in sediment and soil samples. Gazi University Journal of Science, 24 (1): 29-34.

13.    E. Lutz & M. I. Thompson (2012).  Hot block digestion of soil, sediment, waste, and tissue samples for total recoverable Metals, 2012.

14.    Wei, B., Jiang, F., Li, X. & Mu, S. (2009). Spatial distribution and contamination assessment of heavy metals in urban road dusts from Urumqi, NW China. Microchemical Journal, 93:147–152.

15.    Fong, F.T., Chee, P.S., Mahmood, A.A. & Tahir, N.M.(2008). Possible source and pattern distribution of heavy metals content in urban soil at Kuala Terengganu Town Center. The Malaysian Journal of Analytical Sciences, 12 (2): 458-467.

16.    European Commission Director General Environment, ECDGE (2010). Heavy Metals and Organic Compounds from Wastes Used as Organic Fertilizers. Final Rep., July. WPA Consulting Engineers Inc. Ref. Nr. TEND/AML/2001/07/20, pp. 73-74.http://ec.europa.eu/environment/waste/compost/pdf/hm_finalreport.pdf

17.    Wang, M., Bai, Y., Chen, W., Markert, B., Peng, C. & Ouyang, Z. (2012). A GIS technology based potential eco-risk assessment of metals in urban soils in Beijing, China. Environmental Pollution, 161: 235-242.

18.    Martley, E., Gulson, B.L. & Pfeifer, H.R. (2004). Metal concentrations in soils around the copper smelter and surrounding industrial complex of Port Kembla, NSW, Australia. Science of the Total Environment, 325: 113-127.

19.    Li, X. & Feng, L. (2012). Multivariate and geostatistical analyzes of metals in urban soil of Weinan industrial areas, Northwest of China. Atmospheric Environment, 47: 58-65.

20.    Cai, L., Xu, Z., Ren, M., Guo, Q., Hua, X., Hua, G., Wand, H. & Peng, P.(2012). Source identification of eight hazardous heavy metals in agricultural soils of Huizhou, Guangdong Province, China. Ecotoxicology and Environmental Safety,78: 2–8.

21.    Yang, Z., Lu, W., Long, Y., Bao, X. & Yang, Q. (2011). Assessment of heavy metals contamination in urban topsoil from Changchun City, China. Journal of Geochemical Exploration, 108: 27–38.

22.    Wang, Y., Qiao, M., Liu, Y. & Zhu, Y.(2012). Health risk assessment of heavy metals in soils and vegetables from wastewater irrigated area, Beijing-Tianjin city cluster, China. Journal of Environmental Sciences, 24(4): 690–698.

23.    CNEMC (China National Environmental Monitoring Centre) (1990), The background values of Chinese soils, Environmental Science Press of China, Beijing.

 

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